发明名称 METHOD FOR PREPARING A LIGHT OLEFIN USING AN OXYGEN-CONTAINING COMPOUND, AND DEVICE FOR USE THEREOF
摘要 A method for preparing a light olefin using an oxygen-containing compound, and a device for use thereof, more specifically, taking methanol and/or dimethyl ether as main starting materials, using a multi-stage (n≧2) dense phase fluidized bed reactor and a multi-stage (m≧2) catalyst regenerator, which the invention solves the problem in the prior art of the uniformity of catalyst carbon deposition and the carbon content being difficult to control and the light olefin selectivity being low.
申请公布号 US2016304412(A1) 申请公布日期 2016.10.20
申请号 US201315100834 申请日期 2013.12.03
申请人 DALIAN INSTITE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES 发明人 LIU Zhongmin;YE Mao;ZHANG Tao;HE Changqing;WANG Xiangao;ZHAO Yinfeng
分类号 C07C1/20;B01J38/06;B01J29/90;B01J38/12;B01J8/26;B01J29/85 主分类号 C07C1/20
代理机构 代理人
主权项 1. A method for preparing a light olefin using an oxygen-containing compound, comprising the following steps: step a) in which a raw material comprising the oxygen-containing compound is introduced in parallel from n feeding branch lines into 1st to nth secondary reaction zones in a dense phase fluidized bed reactor, and is brought into contact with a catalyst to generate a light olefin product-containing stream and a spent catalyst, wherein said catalyst is sequentially passed through 1st to nth secondary reaction zones, with the carbon content thereof increasing gradually, and wherein said dense phase fluidized bed reactor is divided by a material flow controller into n secondary reaction zones; step b) in which the light olefin product-containing stream flowed out from the 1st to nth secondary reaction zones is separated from the spent catalyst that it carries; said light olefin product-containing stream is passed into a product separation section, and after separation and purification, a light olefin product is obtained; the isolated spent catalyst is passed into the nth secondary reaction zone; and step c) in which the spent catalyst flowed out from the nth secondary reaction zone, after being stripped and lifted, is passed into a dense phase fluidized bed regenerator for regeneration; said spent catalyst is sequentially passed through 1st to mth secondary regeneration zones; a regeneration medium is introduced in parallel from m feeding branch lines of regeneration zone into the 1st to mth secondary regeneration zones; the spent catalyst is brought into contact with the regeneration medium, with the carbon content thereof decreasing gradually; after the completion of the regeneration, the catalyst is returned back to the 1st secondary reaction zone via stripping and lifting; wherein the dense phase fluidized bed regenerator is divided by a material flow controller into m secondary regeneration zones; wherein n>2 and m>2.
地址 Dalian CN