发明名称 METHOD OF CROSSLINKING AROMATIC BORON ACIDS WITH AROMATIC HALOGEN COMPOUNDS OR PERFLUOROALKYL SULPHONATES
摘要 The invention concerns a method of preparing polycyclic aromatic compounds by crosslinking aromatic boron acids with aromatic halogen compounds or perfluoroalkyl sulphonates in the presence of metallic palladium, optionally on a carrier, as catalyst. The method is characterized in that the crosslinking is carried out in the presence of a ligand and a base. The method disclosed enables the yield of polycyclic aromatic compounds to be increased significantly compared with methods in which no ligand is used, i.e. it ensures optimum yields in the pd(O)-catalysed crosslinking of aromatic boron acids with aromatic halogen compounds.
申请公布号 WO9410105(A1) 申请公布日期 1994.05.11
申请号 WO1993EP02733 申请日期 1993.10.06
申请人 HOECHST AKTIENGESELLSCHAFT;SCHLOSSER, HUBERT;WINGEN, RAINER;MANERO, JAVIER 发明人 SCHLOSSER, HUBERT;WINGEN, RAINER;MANERO, JAVIER
分类号 G02F1/13;C07B37/04;C07D213/24;C07D213/30;C07D213/61;C07D213/64;C07D239/26;C07D239/28;C07D239/30;C07D239/80;C07D401/04;C07D401/14;C09K19/34;C09K19/40;(IPC1-7):C07B37/04 主分类号 G02F1/13
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