发明名称 |
Verfahren zur Herstellung von Aldehyden |
摘要 |
The invention relates to the hydroformylation of olefins or of olefinically unsaturated compounds in the presence of an organic solution which serves as a catalyst and which contains at least one rhodium compound and at least one phosphine-substituted cobalticinium salt. The inventive method is characterised in that phosphine-substituted cobalticinium salts of general formula (I), wherein R<1> is the same or varies and is hydrogen or various substituents, are used. An aqueous solution of 1, 1'-bis(diphenylphosphino)-cobalticinium nitrate and a rhodium compound is suitable as a hydroformylation catalyst in a two phase process. |
申请公布号 |
DE19742907(C2) |
申请公布日期 |
2002.11.14 |
申请号 |
DE1997142907 |
申请日期 |
1997.09.29 |
申请人 |
CELANESE CHEMICALS EUROPE GMBH |
发明人 |
BAHRMANN, HELMUT;SALZER, ALBRECHT;BRASSE, CLAUDIA |
分类号 |
B01J31/22;B01J31/24;C07C45/50 |
主分类号 |
B01J31/22 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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