| 主权项 |
1. A compound of formula I,
A-B (I),wherein A is a radical selected from the group consisting of formulae A1 to A8: wherein the arrow denotes the point of attachment to the radical B; and B is a radical selected from the group consisting of formulae B1 to B11: wherein the arrow denotes the point of attachment to the radical A; wherein L1 is methylene or a direct bond; V0 nitrogen or CR5; V1 is nitrogen or CR20; V2 is nitrogen or CR21; V3 is nitrogen or CR22; V4 is nitrogen or CR23; V5 is nitrogen or CR24; V6 is nitrogen or CR25; V7 is nitrogen or CR26; V8 is nitrogen or CR27; V9 is nitrogen, or CR28; V10 is nitrogen or CR29; V11 is nitrogen or CR39; G1 is nitrogen or CR31; G2 is nitrogen or CR32; G3 is —NR35, an oxygen atom or a sulphur atom; G4 is nitrogen or CR33; G5 is nitrogen or CR34; J1, J2, J3 together form together a 5 membered heterocyclic ring, which can be saturated or unsaturated, containing one or two atoms selected from the group consisting of nitrogen, oxygen and sulphur, which ring can be mono- or polysubstituted by substituents selected from the group consisting of C1-C6alkyl, halogen and or C1-C6haloalkyl, with the proviso that if the ring contains two oxygen atoms, or two sulphur atoms, they are separated by one carbon atom; R1 and R2 are the same or different and each represents, hydrogen, halogen, C1-C6alkyl or C1-C6haloalkyl; R3 is a C1-C6alkyl, C2-C6 alkenyl or C2-C6 alkynyl group which can be mono- or polysubstituted by substituents selected from the group consisting of C1-C6alkoxy, C1-C6haloalkoxy, C2-C6alkenyloxy, C2-C6haloalkenyloxy, C2-C6alkynyloxy, C2-C6haloalkynyloxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6haloalkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, cyano, hydroxy, halogen, C3-C6cycloalkyl, said C3-C6cycloalkyl itself can be mono- or polysubstituted by substituents selected from halogen and C1-C3alkyl; and by a 5- or 6-membered heterocyclic group, which can be mono- or polysubstituted by substituents selected from the group consisting of C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6haloalkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, C1-C6alkylamino, C1-C6haloalkylamino, C2-C8dialkylamino, C2-C8halodialkylamino, halogen, cyano and nitro; or R3 is C3-C6cycloalkyl, which can be mono- or polysubstituted by substituents selected from the group consisting of C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C2-C6alkenyloxy, C2-C6haloalkenyloxy, C2-C6alkynyloxy, C2-C6haloalkynyloxy and halogen; or R3 is a 5- or 6-membered heterocyclic group, which can be mono- or polysubstituted by substituents selected from the group consisting of C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6haloalkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, C1-C6alkylamino, C1-C6haloalkylamino, C2-C8dialkylamino, C2-C8halodialkylamino, halogen, cyano and nitro; or R3 is —CO2R36, —C(O)R36 or hydrogen; R35 is hydrogen, C1-C6alkyl which can be mono- or polysubstituted by substituents selected from the group consisting of C1-C6alkoxy, C1-C6haloalkoxy, C2-C6alkenyloxy, C2-C6haloalkenyloxy, C2-C6 alkynyloxy, C2-C6haloalkynyloxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6alkoxycarbonyl, cyano, hydroxy, halogen and C3-C6cycloalkyl, said C3-C6cycloalkyl itself can be mono- or polysubstituted by substituents selected from halogen and C1-C3alkyl; or an N-oxide thereof; R4, R5, R20, R21, R22, R23, R24, R25, R26, R27, R28, R29, and R30 are the same or different and represents cyano, nitro, halogen, hydroxy, C1-C6alkenyloxy, C1-C6-haloalkoxy, C3-C6cycloalkyl, —C(O)R36 or hydrogen; or C1-C6alkyl which can be mono- or polysubstituted by substituents selected from the group consisting of cyano, halogen, hydroxy, C1-C6alkoxy, C1-C6haloalkoxy, C2-C6alkenyloxy, C2-C6haloalkenyloxy, C2-C6alkynyloxy, C2-C6haloalkynyloxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6 alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6haloalkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, cyano, hydroxy, halogen and C3-C6cycloalkyl, said cycloalkyl itself can be substituted by substituents selected from the group consisting of halogen and C1-C3alkyl; or represents a phenyl group which can be mono or polysubstituted by substituents selected from the group consisting of C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6haloalkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, C1-C6alkylamino, C1-C6haloalkylamino, C2-C8dialkylamino, C2-C8halodialkylamino, halogen, cyano, and nitro; R6, R7, R8, R9, R10, R11, R12, R13, R14, R15, R16, R17, R18 and R19 are the same or different and represents C1-C6 alkyl, C1-C6 haloalkyl, or hydrogen, and the group CR13R14 can additionally be a carbonyl group C═O; R31, R32, R33 and R34 are the same or different and represents C1-C6alkyl, C1-C6haloalkyl, —OR7, —S(O)nR36, —NR36R37, —CO2R36, —C(O)R36, cyano, nitro, halogen or hydrogen; R36 and R37 are the same or different and represents hydrogen, C1-C6alkyl which can be mono- or polysubstituted by substituents selected from C1-C6alkoxy, C1-C6haloalkoxy, C2-C6 alkenyloxy, C2-C6haloalkenyloxy, C2-C6alkynyloxy, C2-C6haloalkynyloxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6haloalkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, cyano, hydroxy, halogen and C3-C6 cycloalkyl, wherein said C3-C6 cycloalkyl can be mono- or polysubstituted by substituents selected from the group consisting of halogen and C1-C3alkyl; or R36 and R37 are the same or different and represents a phenyl group which can be mono- or polysubstituted by substituents selected from the group consisting of C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C6alkylsulphanyl, C1-C6haloalkylsulphanyl, C1-C6alkylsulphinyl, C1-C6haloalkylsulphinyl, C1-C6alkylsulphonyl, C1-C6haloalkylsulphonyl, C2-C6alkylcarbonyl, C2-C6haloalkylcarbonyl, C2-C6alkoxycarbonyl, C2-C6haloalkoxycarbonyl, C1-C6alkylamino, C1-C6haloalkylamino, C2-C8dialkylamino, C2-C8halodialkylamino, halogen, cyano, and nitro; each m independently represents 0, 1 or 2, and n represents 0, 1 or 2, with the proviso that:
a) in —S(O)nR36, R36 is hydrogen when n is 0;b) if B is B1, then A is different from A2, A3 and A5;c) if A is A1, then B is different from B1, B7, B8, B9 and B10;d) if A is A5, then B is different from B10; or an agrochemically acceptable salt, enantiomer, diastereomer, tautomer, armor N-oxide thereof. |
