| 摘要 |
Provided is a phthalocyanine-based complex compound which, when applied onto the surface of a metal, (i) has improved adhesion to the metal and (ii) can improve the durability of the metal. The phthalocyanine-based complex compound is characterized by being represented by general formula (1). In general formula (1), M represents any one selected from Cu, Fe, Ti, V, Ni, Pd, Pt, Pb, Si, Bi, Cd, La, Tb, Ce, Be, Mg, Co, Ru, Mn, Cr, Mo, Sn and Zn and may be present or absent; each of R1 to R4 may be present in the number of at least 1 in the phthalocyanine moiety, each of R1 to R4 contains an ion represented by any one of general formulae included in the general formula group (A), and R1 to R4 may be the same as or different from one another; R5 to R7 in the general formula group (A) independently represent a hydrogen atom or a hydrocarbon group and may be the same as or different from one another; each of R1 to R4 also contains a counter ion represented by any one of general formulae included in the general formula group (B); X in the general formula group (B) represents an ion represented by SO3 -, COO-, PO3H-, PO3 2-, N+R8R9R10 or PhN+R8R9R10, an ion represented by general formula (2) or an ion represented by structural formula (1); and R8 to R10 in the general formula group (B), N+R8R9R10, PhN+R8R9R10 and general formula (2) independently represent a hydrogen atom or a hydrocarbon group and may be the same as or different from one another. |
