ISOMERIZATION METHOD FOR BIS (AMINOMETHYL) CYCLOHEXANE

摘要

A method for isomerizing a bis(aminomethyl)cyclohexane, including an isomerization step of isomerizing the bis(aminomethyl)cyclohexane in the presence of an imine compound represented by the following general formula (1) and at least one compound selected from the group consisting of an alkali metal, an alkali metal-containing compound, an alkaline earth metal and an alkaline earth metal-containing compound:;;wherein R1 and R2 each independently represent a hydrogen atom or a monovalent group selected from the group consisting of a substituted or unsubstituted hydrocarbon group, a substituted or unsubstituted alkoxy group, and an acyl group (R1 and R2 may mutually bind to form a ring); R3 represents a hydrogen atom or an n-valent group selected from the group consisting of substituted or unsubstituted hydrocarbon groups; and n represents an integer of 1 to 10.

主权项

1: A method for isomerizing a bis(aminomethyl)cyclohexane, comprising:
an isomerization step of isomerizing the bis(aminomethyl)cyclohexane in the presence of: an imine compound represented by formula (1) and at least one compound selected from the group consisting of an alkali metal, an alkali metal-containing compound, an alkaline earth metal and an alkaline earth metal-containing compound:wherein R1 and R2 each independently represent a hydrogen atom or a monovalent group selected from the group consisting of a substituted or unsubstituted hydrocarbon group, a substituted or unsubstituted alkoxy group, an substituted or unsubstituted aryloxy group and an acyl group (R1 and R2 may mutually bind to form a ring); R3 represents a hydrogen atom or an n-valent group selected from the group consisting of substituted or unsubstituted hydrocarbon groups; and n represents an integer of 1 to 10.