发明名称 PROCESS FOR THE PREPARATION OF 2-(2-HYDROXYPHENYL)-2H-BENZOTRIAZOLES
摘要 2-(2-Hydroxyphenyl)-2H-benzotriazoles of the formula (* CHEMICAL STRUCTURE *) I in which R is hydrogen, C1-C12alkyl or C1-C4alkoxy, R1 is hydrogen, C1-C12alkyl, C5-C6cycloalkyl, phenyl or phenyl-C1-C4alkyl and R2 is C1-C12alkyl, C5-C6cycloalkyl, phenyl, phenyl-C1-C4alkyl or a group -CnH2n-COOR3, in which n is 0 to 4 and R3 is hydrogen or C1-C12alkyl, can be prepared particularly advantageously by catalytic hydrogenation of a suitable o-nitroazo compound in the presence of a Pt, Pd, Pt/Pd or Rh hydrogenation catalyst and an alkylenediamine or an acyclic or cyclic polyalkylene polyamine in a halogenated or nonhalogenated aromatic hydrocarbon as solvent.
申请公布号 KR0152665(B1) 申请公布日期 1998.10.15
申请号 KR19900014834 申请日期 1990.09.19
申请人 CIBA SPECIALTY CHEMICALS HOLDING INC. 发明人 PRESTEL, HELMUT;MAUL, RUDOLF
分类号 B01J23/40;C01B3/00;C07B61/00;C07D249/20;C09K3/00;(IPC1-7):C07D249/20 主分类号 B01J23/40
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