发明名称 Transition metal acetylide compound, nano-powder and method for producing a transition metal acetylide compound
摘要 An anhydrous chloride with a formula of MCl<SUB>2 </SUB>(M-Fe, Co or Ni) is dissolved into an anhydrous acetonitrile solvent to form a chloride-acetonitrile solution. Then, calcium carbide minute powders are added and dispersed in the chloride-acetonitrile solution at a molar quantity equal to or smaller by 1-30 mol % than the molar quantity of the anhydrous chloride to form a reactive solution. Then, the reactive solution is heated at a predetermined temperature to chemically react the anhydrous chloride with the calcium carbide minute powders in the reactive solution to form a transition metal acetylide compound having an M-C<SUB>2</SUB>-M bond, a tetragonal structure, and a formula of MC<SUB>2 </SUB>(herein, M-Fe, Co or Ni).
申请公布号 US2005171370(A1) 申请公布日期 2005.08.04
申请号 US20040944037 申请日期 2004.09.20
申请人 INTER-UNIVERSITY RESEARCH INSTITUTE CORPORATION NATIONAL INSTITUTES OF NATURAL SCIENCE 发明人 NISHI NOBUYUKI;KOSUGI KENTARO
分类号 C01B31/30;C07F15/02;C07F15/04;C07F15/06;(IPC1-7):C07F15/02 主分类号 C01B31/30
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