IMIDAZOTHIAZOLE SUFONAMIDES AS NEMATICIDES

摘要

Disclosed are compounds of formula (I) which possess nematicidal properties;;wherein the structural elements have the meaning as indicated in the description.

主权项

1. A compound of formula (I) wherein A is N or C—R1; Z is O or S; each R1 is independently H, halogen, cyano, nitro, SF5, OCN, SCN, Si(R15)3, OR4, NR5R6, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7, OC(O)OR8, OC(O)NR11R12, OS(O)2R9, OS(O)2NR11R12, N(R10)C(O)R7, N(R10)C(O)NR11R12, N(R10)S(O)2R9 or N(R10)S(O)2NR11R12; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or C1-C6-alkyl substituted with 1 to 4 substituents independently selected from the group consisting of cyano, nitro, OR4, NR5R6, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 and S(O)2NR11R12; or phenyl, naphthalenyl or a 5- or 6-membered heteroaromatic ring, each optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4, NR5R6, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 and S(O)2NR11R12; R2 is H, halogen, cyano, nitro, SF5, OCN, SCN, Si(R15)3, OR4, NR5R6, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C3-C7-cycloalkyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7, OC(O)OR8, OC(O)NR11R12, OS(O)2R9, OS(O)2NR11R12, N(R10)C(O)R7, N(R10)C(O)NR11R12, N(R10)S(O)2R9 or N(R10)S(O)2NR11R12; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or C1-C6-alkyl substituted with 1 to 4 substituents independently selected from the group consisting of cyano, nitro, OR4, NR5R6, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 and S(O)2NR11R12; or phenyl, naphthalenyl or a 5- or 6-membered heteroaromatic ring, each optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4, NR5R6, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 and S(O)2NR11R12, C2-C6-alkoxyalkyl, OC(O)R7a and N(R10)C(O)R7a; R3 is H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 or S(O)2NR11R12; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4a, and S(O)mR9a; or C1-C6-alkyl substituted with 1 to 4 substituents independently selected from the group consisting of cyano, nitro, OR4, NR5R6, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 and S(O)2NR11R12; or C1-C6-alkyl substituted with 1 to 2 substituents independently selected from the group consisting of phenyl or a 5- or 6-membered heteroaromatic ring, each optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4, NR5R6, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C6-alkoxyalkyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7a and N(R10)C(O)R7a; or phenyl optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4, NR5R6, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C6-alkoxyalkyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7a and N(R10)C(O)R7a; Q is phenyl, naphthalenyl, a 5- or 6-membered heteroaromatic ring or an 8- to 10-membered heteroaromatic bicyclic ring system, each optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, SF5, OCN, SCN, Si(R15)3, OR4, NR5R6, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C(X)R7, C(O)OR8, C(X)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7, OC(O)OR8, OC(O)NR11R12, OS(O)2R9, OS(O)2NR11R12, N(R10)C(O)R7, N(R10)C(O)NR11R12, N(R10)S(O)2R9, N(R10)S(O)2NR11R12 and R14; each R4 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, each substituted with 1 to 4 substituents independently selected from the group consisting of, cyano, nitro, OR4a, NR5aR6a, C(X)R7a, C(O)OR8a, C(O)NR11R12, S(O)mR9a and S(O)2NR11R12; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or phenyl optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7a, C(O)OR8a, C(O)NR11R12, OR4a, C2-C6-alkoxyalkyl, S(O)mR9a, S(O)2NR11R12, NR5aR6a, OC(O)R7a and N(R10)C(O)R7a; each R4a is independently H, C1-C6-alkyl or C1-C6-haloalkyl; each R5 is independently H, NR5aR6a, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 or S(O)2NR11R12; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or phenyl optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7a, C(O)OR8a, C(O)NR11R12, OR4a, C2-C6-alkoxyalkyl, S(O)mR9a, S(O)2NR11R12, NR5aR6a, OC(O)R7a and N(R10)C(O)R7a; each R5a is independently H or C1-C6-alkyl; each R6 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; each R6a is independently H, C1-C6-alkyl, C(O)R13 or C(O)OR13; each R7 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or phenyl optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7a, C(O)OR8a, C(O)NR11R12, OR4a, C2-C6-alkoxyalkyl, S(O)mR9a, S(O)2NR11R12, NR5aR6a, OC(O)R7a and N(R10)C(O)R7a; each R7a is independently C1-C6-alkyl or C1-C6-haloalkyl; each R8 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, each substituted with 1 to 4 substituents independently selected from the group consisting of, cyano, nitro, OR4a, NR5aR6a, C(X)R7a, C(O)OR8a, C(O)NR11R12, S(O)mR9a and S(O)2NR11R12; or phenyl optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7a, C(O)OR8a, C(O)NR11R12, OR4a, C2-C6-alkoxyalkyl, S(O)mR9a, S(O)2NR11R12, NR5aR6a, OC(O)R7a and N(R10)C(O)R7a; each R8a is independently C1-C6-alkyl or C1-C6-haloalkyl; each R9 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, each substituted with 1 to 4 substituents independently selected from the group consisting of, cyano, nitro, OR4a, NR5aR6a, C(X)R7a, C(O)OR8a, C(O)NR11R12, S(O)mR9a and S(O)2NR11R12; or phenyl optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7a, C(O)OR8a, C(O)NR11R12, OR4a, C2-C6-alkoxyalkyl, S(O)mR9a, S(O)2NR11R12, NR5aR6a, OC(O)R7a and N(R10)C(O)R7a; each R9a is independently C1-C6-alkyl or C1-C6-haloalkyl; each R10 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C3-C7-cycloalkyl, C(X)R7a, C(O)OR8a, C(O)NR11R12, S(O)mR9a or S(O)2NR11R12; each R11 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, each substituted with 1 to 4 substituents independently selected from the group consisting of, cyano, nitro, OR4a, NR5aR6a, C(X)R7a, C(O)OR8a, C(O)NR11aR12, S(O)mR9a and S(O)2NR11aR12; or phenyl optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7a, C(O)OR8a, C(O)NR11aR12, OR4a, C2-C6-alkoxyalkyl, S(O)mR9a, S(O)2NR11aR12, NR5aR6a, OC(O)R7a and N(R10)C(O)R7a; each R11a is independently H, C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkynyl; each R12 is independently H, NR5aR6a, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 or S(O)2NR11R12; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or phenyl optionally substituted with 1 to 3 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C(X)R7a, C(O)OR8a, C(O)NR11R12, OR4a, C2-C6-alkoxyalkyl, S(O)mR9a, S(O)2NR11R12, NR5aR6a, OC(O)R7a and N(R10)C(O)R7a; each R13 is independently H, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; each R14 is independently C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl, C6-C14-cycloalkylcycloalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or C1-C6-alkyl, C2-C6-alkenyl or C2-C6-alkynyl, each substituted with 1 to 4 substituents independently selected from the group consisting of cyano, nitro, OR4, NR5R6, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9 and S(O)2NR11R12; or phenyl, naphthalenyl or a 5- or 6-membered heteroaromatic ring, each optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4, NR5R6, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C6-alkoxyalkyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7a and N(R10)C(O)R7a; or C1-C6-alkyl substituted with a substituent selected from the group consisting of a 5- or 6-membered heteroaromatic ring, each optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4, NR5R6, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C6-alkoxyalkyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7a and N(R10)C(O)R7a; each R15 is independently C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl or C2-C6-haloalkynyl; or C3-C7-cycloalkyl, C4-C8-cycloalkylalkyl or C5-C7-cycloalkenyl, each optionally substituted with 1 to 4 substituents independently selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, OR4a and S(O)mR9a; or phenyl optionally substituted with 1 to 5 substituents independently selected from the group consisting of halogen, cyano, nitro, OR4, NR5R6, C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C6-alkoxyalkyl, C(X)R7, C(O)OR8, C(O)NR11R12, S(O)mR9, S(O)2NR11R12, OC(O)R7a and N(R10)C(O)R7a; X is O or S; each m is independently 0, 1 or 2; and n is 0, 1 or 2.