CROSSLINKED POLYMERIC BATTERY MATERIALS

摘要

Provided are crosslinked or crosslinkable polymeric materials suitable for use as an electrode binder, separator, protector, or other uses in an electrochemical call. In some aspects, electrode materials are provided that include an electrode active material combined with a binder that is formed of crosslinked polymeric material, optionally PVA crosslinked with lithium tetraborate. The binder material offers the ability to form electrodes in an aqueous solvent thereby bypassing the toxic solvents required by may prior binding systems. Also provided are processes of forming an electrode that include combining an electrode active material with a binder formed in part or wholly from a polymer and a crosslinker to form a slurry, and coating an electrically conductive substrate with the slurry to form the electrode. The binder material used in the processes is compatible with polymerization in an aqueous solvent and compatible with silicon based anode materials and cathode materials suitable for use in a lithium ion cell.