Multi-hetero-macro-ring cpds. contg. binaphthyl units - useful as complexing agents

摘要

Cpds. of formula (I) and (III) where n = 1-3, m (independentaly) = 0-5, B = O.S. imino or tosylimido gp. x = (CH2)vR where v = 1-3 and R = H CH3, COOH, SO3h, PO(OH)2, NH2,N(CH3)2, N(CH2CH2)2O, OH, OCH3, NHCOCH3, CH2oh, CH2Cl, CH2OCH2COOH, CH2OCH2COOCH3, CH2OCH2CH2PO(OH)2, CH2OCH2CH2SO3h, CH2SCH2COOH, CH2CH2COOH or CH2SCH2CH2COOH and Y = H, Br, NH2, COOH, SO3H, CH=CH2, CH2OH, CH3CO, CH2Cl CH2OCH2COOH, Si(CH3)2Cl, CH2Cl, NCO, CH3(ch2)16C(CH3)2, CH3(CH2)17chch3, CH(OH)-polymer, CONH-polymer, SO2NH polymer, NHSO2-polymer, COOCH2-polymer or Si(CH3)2O-polymer. in which polymer = p-substd. polystyrene cross-link with 0-2 wt. % divinylbenzene or silicic acid. The prods. are useful as complexing agents whereby the oxygen atoms in the ring act as neutral ligands for metal-, alkylammonium, aryldiazonium or aryloxycarbonium ions.