Glass article provided with photocatalyst film

摘要

The present invention provides a glass article including a photocatalyst film 1 containing silicon oxide particles 6 and titanium oxide particles 5, and a glass sheet 2. Assuming that the photocatalyst film 1 has a film thickness T, 80% or more of the titanium oxide particles are localized in a region between a surface of the glass sheet 2 and a position spaced from the surface by 0.6 T toward a surface of the photocatalyst film 1 in a thickness direction of the photocatalyst film 1. The glass article has an increased transmittance provided by enhancing the reflection-reducing function of the photocatalyst film 1 while maintaining the film strength and photocatalytic function of the photocatalyst film 1.

主权项

1. A glass article comprising a glass sheet and a photocatalyst film formed on a surface of the glass sheet, wherein
the photocatalyst film contains silicon oxide particles, titanium oxide particles, and a binder material whose main component is silicon oxide, the silicon oxide particles are contained in an amount of 72 to 79 mass %, the titanium oxide particles are contained in an amount of 13 to 18 mass %, and the binder material is contained in an amount of 8 to 12 mass %, with respect to a total amount of the silicon oxide particles, the titanium oxide particles, and the binder material, the silicon oxide particles have an average particle diameter of 50 nm to 150 nm, the titanium oxide particles have an average particle diameter of 5 nm to 20 nm, and the average particle diameter of the silicon oxide particles is five times or more of the average particle diameter of the titanium oxide particles, assuming that the photocatalyst film has a film thickness T, 80% or more of the titanium oxide particles are present between the surface of the glass sheet and a position spaced from the surface of the glass sheet by 0.6 T toward a surface of the photocatalyst film in a thickness direction of the photocatalyst film, and an amount of transmittance increase ΔT is 2.13% to 2.39%, the amount of transmittance increase ΔT being obtained by subtracting an average transmittance in a range of 400 to 1200 nm of the glass sheet having no photocatalyst film formed thereon from an average transmittance in a range of 400 to 1200 nm of the glass article.