发明名称 |
Process for the conversion of a terminal carbon-carbon double bond of an olefinic hydrocarbon to carbonyl groups |
摘要 |
Terminal carbon-carbon double bonds of olefinic hydrocarbons are converted to carbonyl groups by reacting the olefin with oxygen in the presence of (a) a catalyst comprising (i) one or more of the metals palladium, rhodium, ruthenium or iridium, and (ii) copper, (b) a diluent comprising two liquid phases, and (c) a surfactant, provided that when the metal is palladium no alkali or alkaline earth metal is present and the surfactant is dodecyltrimethylammonium or cetyltrimethylammonium chloride or bromide.
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申请公布号 |
US4568770(A) |
申请公布日期 |
1986.02.04 |
申请号 |
US19830536884 |
申请日期 |
1983.09.28 |
申请人 |
THE BRITISH PETROLEUM COMPANY P.L.C. |
发明人 |
ALPER, HOWARD;JANUSZKIEWICZ, KRZYSZTOF R.;SMITH, DAVID J. H. |
分类号 |
C07C45/34;(IPC1-7):C07C45/34 |
主分类号 |
C07C45/34 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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