发明名称 TETRAALKYLPHOSPHONIUM BIS(1,2-BENZENEDITHIOLATO) NICKELATE DERIVATIVE
摘要 NEW MATERIAL:A compound expressed by formula I (R<1>-R<4> represent alkyl; R represents H or methyl; n is 1-4). EXAMPLE:A compound expressed by formula II. USE:An infrared ray absorber, having improved solubility in an organic solvent and compatibility with such as a film-forming binder, superior near infrared ray insulating ability and great transmittance of the visible region and obtainable at a low cost because of ready synthesis. PREPARATION:Normally, a 1,2-benzenedithiol derivative is dissolved into absolute ethanol and neutralized with KOH and an ethanol solution of a nickel salt and a solution of quaternary phosphonium salt are successively added thereinto and stirred in air or while blowing oxygen thereinto to carry out the reaction.
申请公布号 JPS62123192(A) 申请公布日期 1987.06.04
申请号 JP19850263377 申请日期 1985.11.22
申请人 FUJI PHOTO FILM CO LTD 发明人 SUZUKI YOSHIAKI
分类号 C07F15/04;C09K3/00 主分类号 C07F15/04
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