Breaker system for fracturing fluids used in fracturing oil bearing formations

摘要

A method of fracturing a zone of a subterranean formation penetrated by a well bore is shown in which a gelable fracturing fluid is formed by combining an aqueous base fluid and a hydratable polymer. A transition metal crosslinker is added to the aqueous base fluid for crosslinking the hydratable polymer to form a gelled fluid of sufficient viscosity to facilitate fracturing of the formation. A proppant can also be added to the gelable fracturing fluid. The gelled fluid and proppant are then injected into the well bore and into contact with the formation under sufficient pressure to fracture the formation. The gelable fracturing fluid has incorporated therein a delayed release breaker comprising a complex multivalent chelating agent that is released slowly over a period of time to compete with the polymer for the transition metal crosslinker, thereby reducing the viscosity of the fluid.