VERFAHREN UND VORRICHTUNG ZUR PYROLYSE UND ANALYSE

摘要

1388609 Determination of organic carbon &c. ENVIROTECH CORP 8 Dec 1972 [10 Dec 1971] 56796/72 Heading G1B A selected element occurring in a fluid sample in a predetermined form (for example organic carbon in waste waters) is determined by a method comprising (a) removing from the sample (which in the embodiment of the figure has been introduced into boat 21 via port 20) any of the selected element present in a form other than the predetermined form (CO 2 and low mol. wt. organic compounds) by volatilization in zone 12, (b) treating the volatilized products in column 31 to remove from them by sorption components containing the selected element in the predetermined form (the low mol. wt. organic compounds), the residual gases (such as carbon dioxide) passing through water stripper 34 to detector 36, (c) desorbing the sorbed components from column 31, (d) pyrolyzing in zone 14 the desorbed components together with the remainder of the fluid sample (from the boat) to give a gaseous product and (e) determining the gaseous product. The boat may contain copper oxide as oxidation agent for the residue in the boat and for determination of organic carbon the gaseous pyrolysis product may be converted to methane by reaction over nickel catalyst in zone 13. The gas flows are arranged to exclude flow of hydrogen from chamber 16 into zone 14. There is a reference to use of the method above for separate measurement of ammonia and low molecular weight amines, and high molecular weight organic nitrogen compounds, when the detector may be flame thermionic or microcoulometer detector means. The apparatus of Fig.2 (not shown) may be used for an oxidative pyrolysis determination, when the sample is heated in a single zone to a lower temperature for the volatiles-removal step (a) and to a higher temperature for the pyrolysis step (d), and an infrared detector may be used to determine carbon dioxide as gaseous product.