发明名称 FRACTIONATION OF C13 BICYCLIC AROMATIC HYDROCARBONS BY DI OR TRIANHYDRIDE COMPLEX FORMATION
摘要 <p>Mixtures of C13 bicyclic aromatic hydrocarbons containing trimethylnaphthalenes are difficult to fractionate by conventional techniques such as distillation or crystallization. However, by contacting such mixtures with the dianhydride of 1,2,4,5-benzenetetracarboxylic acid, the dianhydride of 1,2,3,4-benezenetetracarboxylic acid or the trianhydride of 1,2,3,4,5,6-benzenehexacarboxylic acid, a solid complex of certain hydrocarbons and the polyanhydride is formed. Separation of the solid complex and its subsequent decomposition results in a complexate that is substantially richer in those trimethylnaphthalenes which are preferentially complexed. These trimethylnaphthalenes can be demethylated to dimethylnaphthalenes which have utility in the production of dyes.</p>
申请公布号 CA950479(A) 申请公布日期 1974.07.02
申请号 CA19710107092 申请日期 1971.03.08
申请人 SUN RESEARCH AND DEVELOPMENT CO. 发明人 DAVIS, RONALD I.
分类号 C07C7/152 主分类号 C07C7/152
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