FARBVERBESSERUNG VON STABILISIERTEN POLYOLEFINHARZEN

摘要

1435464 Removing catalyst residues from olefin polymers DART INDUSTRIES Inc 29 March 1974 [9 April 1973] 14066/74 Heading C3P A stabilized olefin polymer from which catalyst residues have been removed is prepared by incorporating at least one phenolic or benzophenone type stabilizer in an olefin polymer which contains an oxidizable compound of iron or a metal of Group IVa, Va or VIa of the Periodic Table (i.e. those groups containing Ti, V and Cr respectively) and treating the olefin polymer, before or after incorporating the stabilizer, with an oxidizing agent selected from peroxy compounds, air or oxygen, at a temperature below the tacky point of the olefin polymer, the amount of oxidizing agent being at least three times the stoichiometeric amount required to oxidize the metal compound to a higher valency state. Suitable stabilizers specified are t-butylhydroxytoluenes, 3,5-di-t-butyl- 4-hydroxybenzyl phosphonate, tetrakis[methylene(3,5 - di - t - butyl - 4 - hydroxyhydrocinnamate)]methane, 3,5 - di - t - butyl - 4 - hydroxy cinnamic acid octadecyl ester, 1,3,5- trimethyl - 2,4,6 - tris[3,5 - di - t - butyl - 4- hydroxybenzyl]benzene, 2,6 - dioctadecyl pcresol, tris(2-methyl-4-hydroxy-5-t-butyl-phenyl)butane, 4,4 - thiobis - (6 - t - butyl - mcresol), 2,21- methylenebis - (4 - methyl - 6 - tbutylphenol), 1,3,5 - tris(3,5 - di - t - butyl - 4- hydroxybenzyl) - 5 - triazine - 2,4,6 - (1H,3H, 5H)-trione and tri(mixed mono and dinonyl phenyl)phosphite- (all phenolic)-; and 2- hydroxy-4-alkoxybenzophenones. In the examples, polypropylene containing Fe, Ti and also Al residues, is treated. The oxidizing agents used are oxygen and H 2 O 2 .