摘要 |
1328964 Oxa- and thia-diazole derivatives FISONS Ltd 6 Oct 1970 [18 Oct 1969] 51248/69 Heading C2C [Also in Division C1] Novel compounds of formula where R<SP>1</SP> is aryl or substituted aryl, R<SP>2</SP> is alkyl substituted by carboxy (or a functional derivative thereof) or by nitrile and X is O or S are prepared by reacting with R<SP>2</SP>Z or (R<SP>2</SP>) 2 SO 4 where Z is halogen or by reacting with R<SP>2</SP>SH. Functional derivatives include salts, esters and amides. The products are used as herbicides, nematocides and plant growth regulants. 3-(p-Chlorophenyl)-5-mercapto-1,2,4-oxadiazole is prepared by heating p-chlorobenzamidoxime, CS 2 , Et 3 N and pyridine for 3 days and 5- mercapto-3-phenyl-1,2,4,-thiadiazole by heating benzamidoxime, CS 2 , sodium methoxide and ethanol. |