Method of estimating stable state membrane filtration flux

摘要

It is an object of the present invention to provide a method of estimating the maximum value of the flux during long-term stable operation including cleaning of a membrane filtration plant based on measured data of a membrane filtration characteristic during initial membrane filtration. The present invention provides a method in which the maximum flux during stable operation of a new membrane filtration plant for which a membrane module and operating conditions have been specified is estimated from a measured value A of an initial membrane filtration characteristic measured using a liquid to be treated in and a membrane of a membrane module of the new membrane filtration plant, an empirical value of a maximum flux during stable operation of each of a plurality of existing membrane filtration plants having the same or a similar membrane module and operating conditions, and a measured value B of the initial membrane filtration characteristic measured using a liquid to be treated in and a membrane of a membrane module of each of the existing membrane filtration plants.

主权项

1. A method of operating a membrane filtration plant for which a membrane module and operating conditions have been specified, the operating method comprising:
a step of obtaining, by using a computer, a measured value A of an initial membrane filtration characteristic for said membrane filtration plant by making a liquid to be treated permeate through membrane of the membrane module of said membrane filtration plant, wherein said initial membrane filtration characteristic is a constant pressure simple filtration resistance,
wherein in the constant pressure simple filtration resistance, a filtration time and a volume of the liquid which permeates the membrane from starting the filtration are measured at a constant pressure of the liquid before the liquid permeate through the membrane and a constant pressure of the liquid after the liquid permeate through the membrane and a ratio of the filtration time to a square of the volume of the liquid is obtained as the measured value A, a step of obtaining, by using a computer, a maximum flux value that maintains the filtration pressure at a stable condition during an operating time range up to chemical cleaning in a stable state of each of a plurality of existing membrane filtration plants having a membrane module and operating conditions the same as said membrane module and operating conditions and different from the membrane filtration plant for which the membrane module and operating conditions have been specified, by repeatedly verifying whether a filtration pressure is maintained in a stable condition at a constant flux until a chemical cleaning in a stable operation and increasing the constant flux in the case that the filtration pressure is maintained in the stable condition; a step of obtaining, by using a computer, a measured value B of the initial membrane filtration characteristic for each of said existing membrane filtration plants by making a liquid to be treated of the each of the existing membrane filtration plants permeate through membrane of the membrane module of the each of said existing membrane filtration plants, wherein in the each of the existing membrane filtration plants, a filtration time and a volume of the liquid which permeates the membrane from starting the filtration are measured at a constant pressure of the liquid before the liquid permeate through the membrane and a constant pressure of the liquid after the liquid permeate through the membrane and a ratio of the filtration time to a square of the volume of the liquid is obtained as the measured value B; a step of estimating, by using a computer, a maximum flux for said membrane filtration plant, wherein the maximum flux values and the measured values B for said existing membrane filtration plants are plotted on a semi-log plot graph with the measured values B on the log side, an approximated straight-line which shows a semi-log linear relationship between the maximum flux values and the measured values B is obtained from the graph, the measured value A is interpolated or extrapolated on the approximated straight-line, and a maximum flux value corresponding to the measured value A is read as the maximum flux value during stable operation of the membrane filtration plant; and a step of controlling the operating conditions of the membrane module of the membrane filtration plant in which the maximum flux estimated in the step of estimating is defined as a maximum of a flux value in the membrane filtration plant.