发明名称 |
Methyl-di:tert.-butyl:phenol purification - by crystallisation from aq. methanol at low temp. |
摘要 |
<p>Purificn. of 4-methyl-2,6-di-t-butylphenol (I) comprises crystallising at 0-5 degrees C from methanol contg. 3-10 w/w % of water, the ratio of solute to aq. methanol ranging from 1:1 to 1:4. The prod. is made by O-alkylation of phenol then aminomethylation and hydrogenolysis of the resultant N,N-dimethyl-3,5-di-ti-butyl-4-hydroxybenzylamine. Aq. methanol containing 3% of water leads to increased losses of prod. The prod. is a colourless stabiliser for synthetic rubber and polymers, an antioxidant for oils, fuels and other petroleum prods. as stabiliser in foods and drugs. The process removes impurities such as 2,6-di-t-butylphenol 2,4,6-tri-t-butylphenol and 2,6-di-ti-butyl-4-methylcyclohexanone with reduced losses of the desired prod. which is obtd. at a purity of =99.95%.</p> |
申请公布号 |
FR2413349(A1) |
申请公布日期 |
1979.07.27 |
申请号 |
FR19770039665 |
申请日期 |
1977.12.29 |
申请人 |
STERLITAMAXKY OPYTNO PROMYSHLENN |
发明人 |
N. V. ZAKHAROVA, A. G. LIAKUMOVICH, G. I. RUTMAN, Z. S. SHALIMOVA, V. R. DOLIDZE, V. J. BORGARDT ET J. I. MICHUROV |
分类号 |
C07C37/84;C07C39/06;(IPC1-7):07C39/06;07C37/22 |
主分类号 |
C07C37/84 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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