| 摘要 |
The invention relates to a process for preparation of at least one of methacrylic acid and a methacrylic acid ester, and a process for treatment of an aqueous phase comprising at least one organic compound comprising process steps: a1) gas phase oxidation of at least one C4 compound to obtain a reaction phase comprising methacrylic acid; a2) quenching of the reaction phase to obtain a crude aqueous phase comprising methacrylic acid; a3) extraction of at least a part of the methacrylic acid from the crude aqueous phase comprising methacrylic acid into an organic solvent to obtain a crude organic phase comprising methacrylic acid and a first aqueous phase, wherein the first aqueous phase comprises components i. at least 65 wt.%, preferably in the range of from 65 wt.% to 99.9 wt.%, more preferably in the range of from 70 wt.% to 99.8 wt.% water, yet more preferably in the range of from 75 wt.% to 99 wt.%, more preferably in the range of from 76 wt.% to 98.5 wt.%, more preferably in the range of from 77 wt.% to 98 wt.%, even more preferably in the range of from 78 wt.% to 97.5 wt.%, even more preferably in the range of from 79 wt.% to 95 wt.%, yet more preferably in the range of from 80 wt.% to 90 wt.% water, based on the total weight of the first aqueous phase, and ii. not more than 35 wt.%, preferably in the range of from 0.1 wt.% to 35 wt.%, preferably in the range of from 0.2 wt.% to 30 wt.%, more preferably in the range of from 1 wt.% to 25 wt.%, yet more preferably in the range of from 1.5 wt.% to 24 wt.%, more preferably in the range of from 2 wt.% to 23 wt.%, even more preferably in the range of from 2.5 wt.% to 22 wt.%, even more preferably in the range of from 5 wt.% to 21 wt.%, yet more preferably in the range of from 10 wt.% to 20 wt.% of at least one organic compound other than the organic solvent used as extraction agent in process step a3), based on the total weight of the first aqueous phase, wherein the sum of the weight amounts of i. and ii. is 100 wt.%; a4) separation and optionally purification of at least a part of the methacrylic acid from the crude organic phase obtained in process step a3); a5) optionally, esterification of at least a part of the methacrylic acid obtained in step a4); b) extraction of at least a part of, preferably all of the first aqueous phase obtained in step a3) with an extraction agent to form an extraction phase comprising component ii. and a second aqueous phase, the second aqueous phase being depleted in component ii. compared to the first aqueous phase; c) at least partial separation of the second aqueous phase obtained in step b) from the extraction phase obtained in step b); d) optionally, at least partial separation of at least one organic compound from the second aqueous phase obtained in step c), to obtain a third aqueous phase which is depleted in at least one organic compound compared to the second aqueous phase. e) optionally, separation of at least a part of the extraction agent from the extraction phase to obtain an extract comprising at least one component ii.. |
