发明名称 |
Olefin polymerisation catalyst based on silicic acid xerogels - and contg. chromium oxide, leaving low catalyst residues in the polymer |
摘要 |
<p>The catalyst is prepd. by (A) preparing a silicic acid-xerogel by (i) extracting >=60%, pref. >=90% of the water contained in a silicic acid-hydrogen contg. 10-25 (esp. 14-20)% solids (calc. as SiO2), with a 1-4C alkanol and/or a 3-5C alkanone; (ii) drying the gel from (i) at 180 degrees C/10 torr/30 mins. until there is no further wt. loss (xerogel formation); (iii) comminuting the xerogel to a dia. of 20-2000 mu, pref. 40-300 mu; (B) admixing the xerogel with solid, finely divided chromium trioxide at 100-300 degrees C/0.001-250 torr, until the xerogel takes up 0.1-10% (calc. on the xerogel and as Cr) chromium trioxide; (C) maintaining the prod. from (B) in a gas stream free from water and contg. >10 vol. % O2 at 400-1000 degrees C/10-1000 mins. The hydrogel used in (A) comprises spherical particles of dia. 1-8 (pref. 2-6)mm. The catalyst is used for the homo- and co-polymerisation of 2-8C monoolefins and esp. for ethylene in suspension or in the dry phase. It has partic. high productivity.</p> |
申请公布号 |
DE2540277(A1) |
申请公布日期 |
1977.03.24 |
申请号 |
DE19752540277 |
申请日期 |
1975.09.10 |
申请人 |
BASF AG |
发明人 |
MUELLER-TAMM,HEINZ,DIPL.-CHEM.DR.;FRIELINGSDORF,HANS,DIPL.-ING.DR.;MERK,GERHARD,DIPL.-CHEM.DR.;GRUBER,WOLFGANG,DIPL.-CHEM.DR. |
分类号 |
C08F10/00;(IPC1-7):C08F10/00 |
主分类号 |
C08F10/00 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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