发明名称 Substituted quinones or analogues as colouring agents
摘要 The invention relates to protein-adhesive dyes, to the preparation thereof and to preparations comprising same, and to a method for coloring keratin-containing fibers, in particular for coloring human hair.
申请公布号 US9458142(B2) 申请公布日期 2016.10.04
申请号 US201314651747 申请日期 2013.11.14
申请人 Merck Patent GmbH 发明人 Rudolph Thomas;Scheurich Rene Peter
分类号 A61Q5/10;C07D405/12;C07D213/69;A61Q5/06;C07D309/40;A61K8/49;C09B23/14;C09B29/036;C09B29/08;C09B44/10;C09B55/00;C09B57/08;C09B1/26;A61Q5/12;A61Q17/04 主分类号 A61Q5/10
代理机构 Millen White Zelano & Branigan, P.C. 代理人 Millen White Zelano & Branigan, P.C.
主权项 1. A compound of the formula I where E denotes NR4 or O, Sp denotes a bond, alk, —C(O)— or —(CO)-alk,D denotes a colour chromophore,R1, R2 or R3 each, independently of one another, denote —H, -A, —OA-, —(CH2)p—OH, —C(O)OA, COOH or COOX,p denotes an integer from 1 to 4,X is the counterion to the [COO−] group,R4 denotes A,alk denotes a linear or branched or cyclic alkylene group having 1 to 18 C atoms and A denotes a linear or branched alkyl group having 1 to 20 C atoms and/or salts, tautomers, stereoisomers and/or solvates thereof, including mixtures thereof in all ratios, wherein substituent D is a substituent of the formula II, III, IV, V, VI, VII, VIII, IX, X, XI or XII, where Ra, Rj and R′j each, independently of one another, denote A, Rb denotes H or A, Rg and R′g each, independently of one another, denote H, Hal, NA2, CN, COOH, OH, CF3, OA, OC(O)A, C(O)OA, NHC(O)A, NHSO2A, SO2NA2, Rs denotes H, A, NA2, OA or SO3Y, Ri and R′i each, independently of one another, denote H or A, Rc and Rd each, independently of one another, denote H or A, where A may be substituted by at least one OH group, Re denotes an alkyl group having 1 to 6 C atoms which is substituted by at least one group NA2 or NA3Y, Y is an anion of an organic or inorganic acid or a cation, A denotes a linear or branched alkyl group having 1 to 20 C atoms, Hal denotes F, Cl, Br or I and m denotes 0, 1, 2, 3, 4 or 5.
地址 Darmstadt DE