On-line rheological measurements.

摘要

On-line rheological measurements are made utilizing a rheometer (20) of the type in which a first metering pump (24) delivers diverted melt from a process main stream to a capillary passage (30) and a second metering pump (34) returns the diverted melt from the capillary passage (30) to the process main stream and the viscosity of the diverted melt is measured by controlling the rate of flow of the melt to maintain constant the pressure drop between spaced apart locations along the capillary passage (30) and measuring the temperature of the melt in the capillary passage (30). The measurements may be made while controlling the speed of the second metering pump (34) independent of the speed of the first metering pump (24) to maintain the pressure at the exit (66) of the capillary passage (30) essentially constant. The capillary passage (30) is placed in close proximity to the process main stream for maintaining a relatively short residence time during which the diverted melt resides outside the process main stream so as to attain a relatively quick response to changes in the measured viscosity. The rheometer (20) includes a relatively thin plate interposed between first and second blocks, the plate including a slot establishing a chamber between the first and second blocks for providing the capillary passage (30).