摘要 |
<p>The invention presented relates to (a) novel complexes of cobalt salts and copolymers of maleic anhydride, ethylenediamine and epichlorohydrin; (b) electroplating compositions for deposit of zinc-cobalt alloys wherein the cobalt is employed in the form of a complex of the above type; and (c) a process for the electrodeposition of bright zinc-cobalt alloys using the latter compositions. Optionally, the electroplating compositions also contain minor amounts of at least one of poly(ethylenediamine); a polycondensate of a di-alkyl diallylammonium chloride and sulfur dioxide; a polycondensate of ethylenediamine, epichlorohydrin and dichloroethane; a polycondensate of piperazine, formaldehyde, epichlorohydrin and thiourea; the reaction product of dimethylaminopropylamine with epichlorohydrin; a polycondensate of tetraethylenepentamine and epichlorohydrin; the reaction product of imidazole with epichlorohydrin; the reaction product of hexamethylenetetramine with epichlorohydrin; a polycondensate of poly(ethylenediamine) and epichlorohydrin; or a polycondensate of morpholine, imidazole, and epichlorohydrin.</p> |