发明名称 Method of synthesis of block copolymers of vinyl aromatic hydrocarbons and polydimethylsiloxane
摘要 A method for producing, in the presence of both monomers, a block copolymer of a polymer block of a vinyl aromatic hydrocarbon (and/or a conjugated diene) and a block of polydimethysiloxane which comprises adding a vinyl aromatic hydrocarbon, an organo alkali metal promoter, hexamethylcyclotrisiloxane and a polar promoter to a solvent (or to the styrene if no solvent is to be used) at a temperature of 0 degrees to 60 degrees C., allowing the polymerization of the vinyl aromatic hydrocarbon to proceed until the color of the vinyl aromatic hydrocarbon - Li+ species which is initially produced fades, then raising the temperature to 60 degrees to 120 degrees C. wherein the hexamethylcyclotrisiloxane polymerizes at the end of the polystyrene polymer blocks and then terminating the polymerization.
申请公布号 US5296574(A) 申请公布日期 1994.03.22
申请号 US19920990587 申请日期 1992.12.15
申请人 SHELL OIL COMPANY 发明人 HOXMEIER, RONALD J.
分类号 C08G77/42;C08G77/442;(IPC1-7):C08L83/10 主分类号 C08G77/42
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