发明名称 OXIDATION OF SUBSTRATE CONTAINING METHYL, METHYLENE OR METHINE GROUP
摘要 PROBLEM TO BE SOLVED: To oxidize a substrate high in reaction rate, selectivity and conversion rate by oxidizing the substrate containing methyl, methylene or methine group in the presence of a catalyst system consisting of a specific imide compound and a metal cocatalyst, and an aldehyde in an organic solvent. SOLUTION: This method for oxidizing a substrate comprises oxidizing simultaneously the substrate containing methyl, methylene or methine group (e.g.; indane) with a 2-20C aromatic or aliphatic aldehyde (e.g.; acetaldehyde) in the presence of a catalyst system consisting of (A) an imide compound of formula I or II (R1, R2 are each H, OH, a halogen, a 1-20C alkyl, alkenyl or alkoxy, an aryl or the like, and R1 and R2 together form double bond in formula I or form a ring in formula I or II; X is O or OH; (n) is 1-3), (e.g.; N- hydroxysuccinimide) and (B) a cocatalyst containing one or more kinds of elements selected from the group consisting of transition metals and elements belonging to the 2A and 3A groups in the Periodic Table, in an organic solvent to obtain a corresponding oxo compound.
申请公布号 JP2000226339(A) 申请公布日期 2000.08.15
申请号 JP19990332836 申请日期 1999.11.24
申请人 DSM FINE CHEMICALS AUSTRIA GMBH 发明人 ALSTERS PAUL;BOUTTEMY SABINE
分类号 C07D223/10;B01J31/02;B01J31/18;B01J31/20;B01J31/22;B01J31/28;C07B41/06;C07B61/00;C07C27/22;C07C31/00;C07C45/33;C07C45/34;C07C45/35;C07C45/36;C07C47/00;C07C49/00;C07D223/22;(IPC1-7):C07B41/06 主分类号 C07D223/10
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