发明名称 |
Process of production of dehydrolinalyl acetate (I) |
摘要 |
The present invention is related to a novel and improved process for the production of dehydrolinalyl acetate (DLA), which IUPAC name is acetic acid 1-ethynyl-1,5-dimethyl-hex-4-enyl ester, starting from dehydrolinalool (DLL), which IUPAC name is 3,7-dimethyloct-6-en-1-yn-3-ol, by catalytic acetylation. |
申请公布号 |
US9505699(B2) |
申请公布日期 |
2016.11.29 |
申请号 |
US201414889291 |
申请日期 |
2014.05.07 |
申请人 |
DSM IP ASSETS B.V. |
发明人 |
Bonrath Werner;Tschumi Johannes;Aquino Fabrice |
分类号 |
C07C67/08;C07C69/145;B01J31/02;B01J31/26 |
主分类号 |
C07C67/08 |
代理机构 |
Nixon & Vanderhye P.C. |
代理人 |
Nixon & Vanderhye P.C. |
主权项 |
1. A process for the production of dehydrolinalyl acetate (DLA) which is a compound of formula (I): wherein the process comprises reacting dehydrolinalool (DLL) which is a compound of formula (II): with acetic anhydride which is a compound of formula (III): in the presence of at least one catalyst of formula (VIII): wherein M is Zn and x is 2 or M is Sc and x is 3. |
地址 |
Heerlen NL |