发明名称 |
PROCESS FOR PREPARING DIALKYLPHOSPHOROCHLORIDOTHIOATES, THE USE OF THE SO PREPARED COMPOUNDS AS INTERMEDIATES, AND THE USE OF SOME OF THE FINAL PRODUCTS AS INSECTICIDES |
摘要 |
A process for deriving certain O,O-dialkyl phosphorochloridothioates in the substantial absence of contamination by free sulfur and avoiding difficult-tohandle sulfur distillation residue, in which process distillation to recover substantially pure product is carried out in the present of a sulfur-solubilizing agent. The process may be used in separating the desired product from a mixture thereof with sulfur produced by reaction of phosphorus pentasulfide and an alkanol, chlorinating and converting by-product sulfur monochloride to free sulfur. The agent is a liquid aromatic compound having at least ten carbon atoms and selected from alkylated and/or chlorinated naphthalenes and anthracenes, and naphthalene, diphenyl and terphenyls, preferably a naphthalene or naphthalenic oil.
<??>The product O,O-dialkyl phosphorochloridothioates have utility in, for example, the preparation of insecticides. |
申请公布号 |
DE2961111(D1) |
申请公布日期 |
1981.12.10 |
申请号 |
DE19792961111 |
申请日期 |
1979.03.01 |
申请人 |
ETHYL CORPORATION |
发明人 |
ANDERSON, ALFRED PIERRE;WILSON, RILEY WOODROW;NELSON, MARSHALL BUDD |
分类号 |
C07F9/02;C07F9/20;(IPC1-7):C07F9/20;A01N57/12;C10M1/48;C10M3/42;C10M5/24;C10M7/46 |
主分类号 |
C07F9/02 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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