Supramolecular Networks with Electron Transfer in Two Dimensions

摘要

Organic charge-transfer (CT) co-crystals in a crossed stack system are disclosed. The co-crystals exhibit bidirectional charge transfer interactions where one donor molecule shares electrons with two different acceptors, one acceptor face-to-face and the other edge-to-face. The assembly and charge transfer interaction results in a pleochroic material whereby the optical absorption continuously changes depending on the polarization angle of incident light.

主权项

1. An organic charge-transfer (CT) co-crystal in a crossed stack lattice exhibiting bidirectional CT interactions, where one donor molecule shares electrons with two different acceptors; wherein one acceptor is face-to-face with the donor and a second acceptor is edge-to-face with the donor, and wherein the co-crystal exhibits visible pleochroism with RGB and CMYK colors.