发明名称 Copolymers of conjugated dienes and vinyl organophosphines prepared by anionic polymerization
摘要 A process for preparing a copolymer including one or more phosphorus-containing mer units, the process comprising anionically polymerizing conjugated diene monomer, vinyl organophosphine monomer, and optionally monomer copolymerizable therewith.
申请公布号 US9499651(B2) 申请公布日期 2016.11.22
申请号 US201414206370 申请日期 2014.03.12
申请人 Bridgestone Corporation 发明人 Hogan Terrence E.;Hergenrother William L.
分类号 C08F130/02;C08F236/10 主分类号 C08F130/02
代理机构 代理人 Hooker Meredith E.;Reginelli Arthur M.
主权项 1. A process for preparing a copolymer including one or more phosphorus-containing mer units, the process comprising: providing an anionic initiator, and combining conjugated diene monomer, vinyl organophosphine monomer, and optionally monomer copolymerizable therewith with the anionic initiator to anionically polymerize the conjugated diene monomer, vinyl organophosphine monomer, and optionally monomer copolymerizable therewith, where the vinyl organophosphine is defined by the formula I: where R1 and R2 are each independently monovalent organic groups, or where R1 and R2 join to form a divalent organic group, and where R3, R4, and R5 are each independently hydrogen or monovalent organic groups, or where R3 and R4 join to form a divalent organic group, where the copolymer including one or more phosphorus-containing mer units is a linear copolymer.
地址 Tokyo JP