| 摘要 |
<p>An anisotropic elastomeric membrane preferably made from polyurea/urethane is described. These anisotropic membranes may be made from the corresponding polymeric material by preparing the polymeric material in a good solvent containing less than 5 vol% non-solvent, producing a film of the polymer solution on a support with a maximum pore size less than 20 microns ( mu m), subjecting the film to conditions such that the solvent vapor pressure-time factor is 1000 mm Hg (133 kPa)-min. or less, preferably 200 mm Hg (26.5 kPa)-min or less, most preferably approaching 0 mm Hg (0 kPa)-min and quenching the membrane film in a non-solvent yielding a three-layered anisotropic membrane. The preferred anisotropic membranes made from the polyurea/urethane copolymer, useful for the separation of aromatics from mixtures thereof with non-aromatics and saturates, in, for example, a naphtha feed stream, are characterized by possessing a urea index of at least about 20% but less than 100%, an aromatic carbon content of at least about 15 mole percent, a functional group density of at least about 10 per 1000 grams of polymer and a C=O/NH ratio of less than about 8.0.</p> |
