摘要 |
<p>In a process for preparing a catalyst for producing methacrylic acid represented by the formula, PaMobVcCudBieXfYgOh wherein P, Mo, V, Cu, Bi and O are phosphorus, molybdenum, vanadium, copper, bismuth and oxygen, respectively, X is at least one element selected from the group consisting of potassium, rubidium, cesium and thallium, Y is at least one element selected from the group consisting of antimony, zinc, iron, cerium, magnesium, chromium, indium, tellurium, manganese, tin, germanium, arsenic, boron, silicon, selenium, zirconium, silver, tantalum and tungsten, a, b, c, d, e, f, g and h are an atomic ratio of each element, and when b is 12, a is 0.1 to 3, c is 0.01 to 2, d is 0.01 to 2, e is 0.05 to 1, f is 0.01 to 2 and g is 0.01 to 5 and h is the number of oxygen atoms necessary to satisfy the valence of each component, the improvement comprising using at least one bismuth compound selected from the group consisting of bismuth nitrate and bismuth oxide as a source of bismuth and using nitric acid of more than 1 mole to not more than 5 moles based on 12 moles of molybdenum atoms for dissolving the bismuth compound(s). The catalyst obtainable by this process and its use are also disclosed.</p> |
申请人 |
MITSUBISHI RAYON CO., LTD. |
发明人 |
YAMAMOTO, SHINJI, C/O CENTRAL RESEARCH LAB.;KINOSHITA, YUTAKA, C/O CENTRAL RESEARCH LAB.;USUI, MASAKO, C/O CENTRAL RESEARCH LAB.;OH-KITA, MOTOMU, C/O CENTRAL RESEARCH LAB. |