发明名称 Water-soluble phosphine-derivatives.
摘要 <p>The invention is concerned with novel water-soluble racemic or optically active compounds of formulae &lt;CHEM&gt; wherein R&lt;1&gt;,R&lt;2&gt;, R&lt;3&gt; and R&lt;4&gt; independently signify lower alkyl or lower alkoxy; m and n are 0, 1 or 2; X signifies hydrogen, an alkali metal, the equivalent of an earth alkali metal or an ammonium ion; with the provisio that R&lt;3&gt; and R&lt;4&gt; are not located at postion 3 or 3'. The invention is also concerned with a process for the manufacture of such compounds, complexes of such compounds with a metal of Group VIII and with the use of these complexes as catalyst for asymmetric hydrogenation and for enantioselective hydrogen displacement in prochiral allylic systems.</p>
申请公布号 EP0667350(A1) 申请公布日期 1995.08.16
申请号 EP19950101105 申请日期 1995.01.27
申请人 F. HOFFMANN-LA ROCHE AG 发明人 LALONDE, MICHEL;SCHMID, RUDOLF
分类号 C07D487/04;B01J31/22;B01J31/24;C07B53/00;C07B61/00;C07C29/17;C07C33/025;C07C51/36;C07C57/58;C07F9/50;C07F15/00;(IPC1-7):C07F9/50 主分类号 C07D487/04
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