发明名称 A PROCESS FOR PRODUCING WATER-ABSORBENT POLYMER PARTICLES BY POLYMERIZING DROPLETS OF A MONOMER SOLUTION
摘要 The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution comprising less than 0.3% by weight of persulfate and at least 0.05% by weight of azo initiator and thermal aftertreatment of the formed polymer particles at less than 100° C. in a fluidized bed for 60 to 300 minutes.
申请公布号 US2016272745(A1) 申请公布日期 2016.09.22
申请号 US201314442501 申请日期 2013.11.11
申请人 BASF SE 发明人 Daniel Thomas;Herfert Norbert;Bauer Stephan;Baumann Katrin;Reinhard Birgit;Freiberg Jürgen;Schliwa Rudolf
分类号 C08F220/06;B01J20/28;B01J20/26;A61L15/24;A61L15/60 主分类号 C08F220/06
代理机构 代理人
主权项 1. A process for producing water-absorbent polymer particles by polymerizing droplets of a) at least one ethylenically unsaturated monomer which bears an acid group and optionally is at least partly neutralized, b) at least one crosslinker, c1) less than 0.3% by weight, based on monomer a), of at least one persulfate, c2) at least 0.05% by weight, based on monomer a), of at least one azo initiator, d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a), e) optionally one or more water-soluble polymer, and f) water, in a surrounding heated gas phase in a reaction zone and thermal posttreatment in a fluidized bed, wherein a temperature of a gas leaving the reaction zone is less than 150° C., a temperature of the water-absorbent polymer particles during the thermal posttreatment is less than 100° C., and a residence time of the water-absorbent polymer particles in the fluidized bed is from 60 to 300 minutes.
地址 Ludwigshafen DE