POLYTUBULAR STRUCTURAL METAL COMPLEX AND METHOD FOR PRODUCING THE SAME

摘要

PROBLEM TO BE SOLVED: To obtain a metal complex compound having a precise host lattice structural hole for incorporating a large compound without any through-structure and to provide a method for producing the metal complex compound. SOLUTION: This polytubular structural metal complex comprises a panel-like ligand (P.L) having >=4 coordinating atoms and two of lines connecting two thereof parallel in the coordinating atom plane or a panel-like ligand represented by the general formula 1 (M.L)X-A (1) (M.L is a substituent group having a coordinating atom N of a metal compound with a metal; A is a tetra- or a polyvalent organic compound residue binding to M.L; and 4<=X) having >=4 coordinating atoms in the substituent group and two of lines connecting two thereof parallel in the coordinating atom plane and the metal compound are two-dimensionally assembled in the direction intersecting the tubular axis by forming and coordinately binding the coordinating atoms of the panel-like ligand into a tubular structure without any penetration structure to further develop the assembled structure in the direction (T.A) intersecting the assembling direction by an affinity or are assembled by forming the tubular structure and coordinately binding the coordinating atoms in the tubular axis direction (T.A) to further develop the assembled structure in the direction intersecting the assembly by coordinate bonds.