摘要 |
To provide a mixed carbon material used for an electrode of a nonaqueous secondary battery with excellent characteristics satisfying both rapid charge-discharge characteristics and high cycle characteristics. A negative electrode material for nonaqueous electrolyte secondary battery, comprising the following carbon material A and carbon material B:
(Carbon material A)
a multilayer-structure carbon material containing a graphitic particle and an amorphous carbon covering the surface of the graphitic particle, which is a carbon material where the interplanar spacing (d002) of 002 planes by the wide-angle X-ray diffraction method is 3.37 Å or less, Lc is 900 Å or more, the tap density is 0.8 g/cm 3 or more, and the Raman R value that is a ratio of the peak intensity near 1,360 cm -1 to the peak intensity near 1,580 cm -1 in the argon ion laser Raman spectrum, is from 0.25 to 0.6,
(Carbon material B)
a graphitic particle where the interplanar spacing (d002) of 002 planes by the wide-angle X-ray diffraction method is 3.37 Å or less, Lc is 900 Å or more, the tap density is 0.8 g/cm 3 or more, the Raman R value that is a ratio of the peak intensity near 1,360 cm -1 to the peak intensity near 1,580 cm -1 in the argon ion laser Raman spectrum, is from 0.2 to 0.5, and the average degree of circularity as determined by a flaw-type particle analyzer is 0.9 or more. |