| 摘要 |
A discharge ionization source, for use for example with an ion mobility spectrometer or atmospheric pressure ionization mass spectrometry. The source uses two or more electrodes for ionization and control, and solid state circuitry for operation. Inductive coupling of the discharge gap to the electronics is not necessary. The source can be operated as a continuous dc discharge, or as a pulsed discharge. The two-electrode configuration provides an anode and cathode with an optional adjustable gap. One of the electrodes can be hollow to enhance ionization efficiency (e.g., hollow cathode) and/or to accept effluent from a gas or liquid (including electrophoresis) chromatographic column. The three-electrode configuration adds a third or control electrode to additionally stabilize the discharge. The third electrode may be biased at the potential of the anode through a ballast resistor, and be located near the cathode. When used in this manner, the third electrode pre-ionizes the gas in the wider discharge gap, and initiates the discharge with a lower breakdown potential. The third electrode may also be used to switch the mode of operation of the discharge source from a gas phase ionizer to an electrospray ionizer. The discharge is pulsed and/or initiated by applying a potential (dc or pulsed) to the cathode. A transistor switch capacitively coupled to a negative diode clipping circuit may be used to double the potential applied across the discharge gap. The average power dissipation is less than a watt.
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