Method for producing alumina

摘要

The invention relates to metallurgy, in particular to acidic methods for producing alumina, and can be used in processing low-grade aluminum-containing raw material. The method for producing alumina comprises roasting an aluminum-containing raw material, treating said material with hydrochloric acid, salting out aluminum chloride by saturating the clarified chloride solution with gaseous hydrogen chloride, calcining aluminum chloride to produce aluminum oxide, and pyrohydrolyzing the mother liquor, with the return of hydrogen chloride to the acid treatment and salting out stages. To improve the quality of the alumina and to reduce energy consumption, the aluminum chloride, precipitated during the salting-out process, is treated with aqueous ammonia, the resulting precipitate is sent to calcination, and the ammonium chloride solution is mixed with said aluminum-containing raw material before or during the roasting thereof, ammonia released during the roasting is dissolved in water, and the resulting aqueous ammonia is sent to the treatment of aluminum chloride. The ammonium chloride solution, prior to mixing with the aluminum-containing raw material, may be subjected to stepwise evaporation with the repeated use of heating steam. The ammonium chloride released during the evaporation can be mixed with the aluminum-containing raw material.

主权项

1. A method for producing alumina, comprising:
mixing and roasting an aluminum-containing raw material with an ammonium chloride solution to produce a roasted raw material wherein said roasted raw material undergoes partial thermal activation and the ammonium chloride undergoes decomposition; dissolving the ammonia released during the roasting in water to form aqueous ammonia; treating said roasted raw material with hydrochloric acid to produce a slurry comprising a solid phase and a clarified chloride solution; salting out aluminum chloride by saturating the clarified chloride solution with gaseous hydrogen chloride to produce a mother liquor and aluminum chloride hexahydrate in crystalline form; subjecting the aluminum choride hexahydrate in crystalline form to treatment by the aqueous ammonia previously produced, to forming boehmite and an ammonium chloride solution; calcining the boehmite to produce aluminum oxide; and pyrohydrolyzing the mother liquor to form hematite and hydrochloric acid, wherein the hydrochloric acid is used in the treating of the roasted raw material step and the salting out aluminum chloride step.