发明名称 |
2,3-Dihydro-2,2-dimethyl-7-isopropyl benzofuran and 2-(2,3-dihydro-2,2-dimethyl-7-benzofuranyl)isopropyl hydroperoxide |
摘要 |
A process for the preparation of carbofuran which process comprises converting sigma -isopropylphenol to 2,3-dihydro-2,2-dimethyl-7-isopropylbenzofuran (I); reacting (I) with an oxygen containing gas to form 2-(2,3-dihydro-2,2-dimethyl-7-benzofuranyl)-isopropyl hydroperoxide (II); catalytically decomposing (II) to form 2,3-dihydro-2,2-dimethyl-7-hydroxybenzofuran (III); reacting (III) with methyl isocyanate to form 2,3-dihydro-2,2-dimethyl-7-benzofuranyl N-methylcarbamate (carbofuran) and recovering said carbamate. New compounds useful as intermediates in the above process are also described.
|
申请公布号 |
US3929837(A) |
申请公布日期 |
1975.12.30 |
申请号 |
US19750541662 |
申请日期 |
1975.01.16 |
申请人 |
ICI AUSTRALIA LIMITED |
发明人 |
SERBAN, ALEXANDER;ENGEL, PHILLIP KNOX |
分类号 |
C07C37/055;C07D307/79;C07D307/86;(IPC1-7):C07D307/79 |
主分类号 |
C07C37/055 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|