SOLID INSOLUBLE METAL CO-ORDINATION COMPLEXES AND THEIR USE AS CATALYSTS

摘要

1483357 Insoluble catalysts RHONEPROGIL 9 Sept 1974 [10 Sept 1973] 39202/74 Heading C1A [Also in Division C5] A solid, insoluble co-ordination complex contains the group of formula wherein is a radical of an insoluble co-ordinating compound in which A represents a silica or alumina residue and Q is a radical containing at least one aliphatic, aromatic or heterocyclic primary, secondary or tertiary amino group or a radical containing a carboxylic acid group, M is a transition metal of group VIII other than iron, nickel or cobalt, preferably Rh, Ru, Pd or Pt, L1 and L11 each independently represents a biphyllic co-ordinating compound or chlorine and n and q each independently represents 0 or an integer from 1 to 6, the free valencies of the Si atom being satisfied by alkyl, phenyl, alkoxy, carboxy, silayan or halogen.