发明名称 SEPARATING AGENT FOR OPTICAL ISOMER
摘要 Provided is a complex obtained by reacting a polymer compound derivative obtained by modifying part of the hydroxy groups or amino groups of a polymer compound having the hydroxy groups or amino groups with a compound represented by the following general formula (I) with one or more kinds of compounds represented by the following general formulae (II) to (V) : (I) A-X—Si (Y)nR3-n; (II) M(OR1)nR24-n; (III) Al (OR1)pR23-p; (IV) Mg (OR1)qR22-q; and (V) [Si (OR3)nR43-n]—(X)—[Si (OR5)nR63-n].
申请公布号 US2016326267(A1) 申请公布日期 2016.11.10
申请号 US201615217519 申请日期 2016.07.22
申请人 NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITY ;DAICEL CHEMICAL INDUSTRIES, LTD. 发明人 OKAMOTO Yoshio;YAMAMOTO Chiyo;IKAI Tomoyuki;KAMIGAITO Masami
分类号 C08B3/14;B01J20/286;B01J20/285;C08B33/00;B01J20/29 主分类号 C08B3/14
代理机构 代理人
主权项 1. A method of producing a complex, the method comprising the steps of: dissolving a polysaccharide derivative obtained by modifying part of hydroxy or amino groups of a polysaccharide with a compound represented by the following general formula (I) and one or more kinds of compounds represented by the following general formulae (II) to (V) in an organic solvent to prepare a solution; and dropping the solution into an aqueous solution of a surfactant or a proton-donating solvent while stirring the aqueous solution or the solvent: A-X—Si(Y)nR3-n   (I) where A represents a reactive group which reacts with a hydroxy or amino group, X represents an alkylene group which has 1 to 18 carbon atoms and which may have a branch, or an arylene group which may have a substituent, Y represents a reactive group which reacts with a silanol group to form a siloxane bond, R represents an alkyl group which has 1 to 18 carbon atoms and which may have a branch, or an aryl group which may have a substituent, and n represents an integer of 1 to 3; M(OR1)nR24-n   (II)Al(OR1)pR23-p   (III)Mg(OR1)qR22-q   (IV) where M represents silicon (Si), titanium (Ti), zirconium (Zr), or chromium (Cr), Al represents aluminum, Mg represents magnesium, R1 represents hydrogen or an alkyl group having 1 to 12 carbon atoms, R2 represents an alkyl group which has 1 to 18 carbon atoms and which may have a branch or an aryl group which may have a substituent, n represents an integer of 1 to 4, p represents an integer of 1 to 3, and q represents an integer of 1 or 2; [Chem 11][Si(OR3)nR43-n]—(X)—[Si(OR5)nR63-n]  (V) where R3, R4, R5, and R6 each independently represent an alkyl group which has 1 to 18 carbon atoms and which may have a branch or an aryl group which may have a substituent, and X represents an alkylene group which has 1 to 18 carbon atoms and which may have a branch or an arylene group which may have a substituent.
地址 Nagoya-shi JP