发明名称 Transition metal tris-dithiolene and related complexes as precursors to active catalysts.
摘要 <p>The present invention is based on the discovery that certain transition metal containing complexes thermally decompose to form solids containing the transition metal, sulfur and carbon and that these transition metal, sulfur and carbon containing solids are particularly suitable as catalysts for hydrodesulfurization, hydrodenitrogenation and aromatics hydrogenation. The transition metal complexes that are thermally decomposed to novel catalysts are complexes of the type represented by the general formula ML&lt;n&gt;3, wherein M is selected from Mo, W, Re and mixtures thereof, L is a dithiolene or aminobenzenethiolate ligand, and n represents the total charge of the metal complexes, and is 0, -1, or -2.</p>
申请公布号 EP0408321(A1) 申请公布日期 1991.01.16
申请号 EP19900307554 申请日期 1990.07.10
申请人 EXXON RESEARCH AND ENGINEERING COMPANY 发明人 HALBERT, THOMAS RISHER;CHIANELLI, RUSSELL ROBERT;STIEFEL, EDWARD IRA;JACOBSON, ALLAN JOSEPH
分类号 B01J27/04;B01J31/22 主分类号 B01J27/04
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