发明名称 METHOD FOR PRODUCING CORE-SHELL CATALYST PARTICLES
摘要 The present invention is to provide a method for producing core-shell catalyst particles with high catalytic activity per unit mass of platinum. Disclosed is a method for producing core-shell catalyst particles including a core containing palladium and a shell containing platinum and covering the shell, wherein the method includes: a step of depositing copper on the surface of the palladium-containing particles by applying a potential that is nobler than the oxidation-reduction potential of copper to the palladium-containing particles in a copper ion-containing electrolyte, and a step of forming the shell by, after the copper deposition step and inside the reaction system kept at -3°C or more and 10°C or less, substituting the copper deposited on the surface of the palladium-containing particles with platinum by bringing the copper into contact with a platinum ion-containing solution in which platinum ions and a reaction inhibitor that inhibits a substitution reaction between the copper and the platinum, are contained.
申请公布号 EP3106223(A1) 申请公布日期 2016.12.21
申请号 EP20140882348 申请日期 2014.12.22
申请人 TOYOTA JIDOSHA KABUSHIKI KAISHA 发明人 KANEKO, Keiichi;KIMURA, Hiroko;ADACHI, Makoto
分类号 B01J37/34;B01J23/44;B01J35/08;C23C18/42;C25D7/00;H01M4/86;H01M4/88;H01M4/92 主分类号 B01J37/34
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