发明名称 メタクリル酸グリシジルの製造法
摘要 PROBLEM TO BE SOLVED: To provide a method for producing glycidyl methacrylate from alkali metal salt of methacrylic acid and epichlorohydrin, in which the deterioration of interfacial properties during removal of the by-produced alkali metal hydrochloride by water washing is prevented.SOLUTION: In a process for obtaining an alkali metal salt of methacrylic acid from methacrylic acid and alkali metal carbonate, an alkali metal carbonate in which water-insoluble matter is removed beforehand, is used. By using an alkali metal carbonate in which water-insoluble matter has been removed, insoluble solids near the interface at the time of water-washing operation for removing the alkali metal hydrochloride which is by-produced during the reaction of alkali metal salt of methacrylic acid and epichlorohydrin to obtain glycidyl methacrylate, no longer occurs and a clear interface can be obtained, and the loss of the oil layer discharged together with the water layer can be suppressed.
申请公布号 JP6044264(B2) 申请公布日期 2016.12.14
申请号 JP20120236301 申请日期 2012.10.26
申请人 三菱瓦斯化学株式会社 发明人 鈴木 周;高橋 淳一
分类号 C07D303/16;C07D301/30 主分类号 C07D303/16
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