Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

摘要

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Arthropoda, Mollusca, and Nematoda, processes to produce such molecules, intermediates used in such processes, pesticidal compositions containing such molecules, and processes of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematicides. This document discloses molecules having the following formula (“Formula One”).;

主权项

1. A molecule having the following formulawherein:
(A) L1 is selected from the group consisting of (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C1-C4)alkyl-O—(C1-C4)alkyl, and (C1-C4)alkyl-N(Rx)—(C1-C4)alkyl,
wherein each alkyl, haloalkyl, cycloalkyl, alkenyl, and alkynyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, and (C2-C6)alkynyl, phenyl, furanyl, pyridazinyl, pyridyl, and thienyl;wherein each phenyl, furanyl, pyridazinyl, pyridyl, and thienyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and phenoxy; (B) Het is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur, or oxygen, and where L1 and Ar1 are not ortho to each other, but may be meta or para, such as, for a five-membered ring they are 1,3, and for a 6-membered ring they are either 1,3 or 1,4,
wherein each heterocyclic ring may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, oxo, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, and C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl,wherein each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, and alkynyl substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and phenoxy; (C) Ar1 is selected from the group consisting of furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, or thienyl,
wherein each furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, and thienyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and phenoxy,wherein each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and phenoxy; (D) R15 is selected from the group consisting of H, (C1-C4)alkyl, (C3-C8)cycloalkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C6)alkyl, C(O)—NRxRy, C(O)-phenyl, (C1-C6)alkyl-NRxRy, C(O)O—(C1-C6)alkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)O—(C1-C4)alkyl,
wherein each alkyl, cycloalkyl, alkenyl, alkynyl, and phenyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, oxo, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C6)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and phenoxy; (E) Q1 is selected from the group consisting of O and S; (F) Q2 is selected from the group consisting of O and S; (G) R16 is selected from the group consisting of (J), H, (C1-C4)alkyl, (C3-C8)cycloalkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, C(O)—(C1-C4)alkyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, (C1-C4)alkylphenyl, (C1-C4)alkyl-O-phenyl, C(O)—(Het-1), Het-1, (C1-C4)alkyl-(Het-1), (C1-C4)alkyl-OC(O)—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)O—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—NRxRy, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl-(Het-1), (C1-C4)alkyl-C(O)-(Het-1), (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl(NRxRy)—C(O)OH, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl-NRxRy, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl-N(Rx)—C(O)O—(C1-C4)alkyl, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl(N(Rx)—C(O)O—(C1-C4)alkyl)-C(O)OH, (C1-C4)alkyl-C(O)-(Het-1)-C(O)O—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)O—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—(C3-C8)cycloalkyl, (C1-C4)alkyl-OC(O)—(Het-1), (C1-C4)alkyl-OC(O)—(C1-C4)alkyl-N(Rx)—C(O)O—(C1-C4)alkyl, (C1-C4)alkyl-NRxRy, (C1-C4)alkyl-S(O)n-(Het-1), and (C1-C4)alkyl-O-(Het-1),
wherein each alkyl, cycloalkyl, alkenyl, alkynyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)H, C(O)OH, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl), phenyl, phenoxy, Si((C1-C4)alkyl)3, S(O)n—NRxRy, and (Het-1); (H) R17 is selected from the group consisting of (J), H, (C1-C4)alkyl, (C3-C8)cycloalkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, C(O)—(C1-C4)alkyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, (C1-C4)alkylphenyl, (C1-C4)alkyl-O-phenyl, C(O)—(Het-1), Het-1, (C1-C4)alkyl-(Het-1), (C1-C4)alkyl-OC(O)—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)O—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—NRxRy, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl-(Het-1), (C1-C4)alkyl-C(O)-(Het-1), (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl(NRxRy)—C(O)OH, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl-NRxRy, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl-N(Rx)—C(O)O—(C1-C4)alkyl, (C1-C4)alkyl-C(O)—N(Rx)(C1-C4)alkyl(N(Rx)—C(O)O—(C1-C4)alkyl)-C(O)OH, (C1-C4)alkyl-C(O)-(Het-1)-C(O)O—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)O—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—(C1-C4)alkyl, (C1-C4)alkyl-OC(O)—(C3-C8)cycloalkyl, (C1-C4)alkyl-OC(O)—(Het-1), (C1-C4)alkyl-OC(O)—(C1-C4)alkyl-N(Rx)—C(O)O—(C1-C4)alkyl, (C1-C4)alkyl-NRxRy, (C1-C4)alkyl-S(O)n-(Het-1), and (C1-C4)alkyl-O-(Het-1),
wherein each alkyl, cycloalkyl, alkenyl, alkynyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)H, C(O)OH, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, phenoxy, Si((C1-C4)alkyl)3, S(O)n—NRxRy, and (Het-1); (I) L2 is selected from the group consisting of (C3-C8)cycloalkyl, phenyl, (C1-C4)alkylphenyl, (C1-C4)alkyl-O-phenyl, (C2-C6)alkenyl-O-phenyl, (Het-1), (C1-C4)alkyl-(Het-1), and (C1-C4)alkyl-O-(Het-1),
wherein each alkyl, cycloalkyl, alkenyl, phenyl, and (Het-1) may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)H, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C1-C4)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, O—(C1-C4)alkyl, S—(C1-C4)alkyl, (C1-C4)alkyl-O—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, phenoxy, and (Het-1),wherein each alkyl, cycloalkyl, alkenyl, phenyl, and (Het-1) substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, NRxRy, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)H, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C1-C4)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, O—(C1-C4)alkyl, S—(C1-C4)alkyl, (C1-C4)alkyl-O—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, phenoxy, and (Het-1); (J) R16 and R17 along with Cx(Q2)(Nx), form a 4- to 7-membered saturated or unsaturated, hydrocarbyl cyclic group, which may further contain one or more heteroatoms selected from the group consisting of nitrogen, sulfur, and oxygen,
wherein said hydrocarbyl cyclic group may be optionally substituted with one or more substituents independently selected from the group consisting of oxo, R18, and R19,wherein R18 and R19 are each independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, oxo, thioxo, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)H, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and (Het-1); (K) Rx and Ry are each independently selected from the group consisting of H, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)H, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, and phenyl,
wherein each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, and phenyl may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)H, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and (Het-1); (L) (Het-1) is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur, or oxygen,
wherein each heterocyclic ring may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, oxo, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and phenoxy,wherein each alkyl, haloalkyl, cycloalkyl, alkoxy, haloalkoxy, alkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from the group consisting of H, F, Cl, Br, I, CN, NO2, (C1-C4)alkyl, (C1-C4)haloalkyl, (C3-C8)cycloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C2-C6)alkenyl, (C2-C6)alkynyl, S(O)n—(C1-C4)alkyl, S(O)n—(C1-C4)haloalkyl, OSO2—(C1-C4)alkyl, OSO2—(C1-C4)haloalkyl, C(O)—NRxRy, (C1-C4)alkyl-NRxRy, C(O)—(C1-C4)alkyl, C(O)O—(C1-C4)alkyl, C(O)—(C1-C4)haloalkyl, C(O)O—(C1-C4)haloalkyl, C(O)—(C3-C8)cycloalkyl, C(O)O—(C3-C8)cycloalkyl, C(O)—(C2-C6)alkenyl, C(O)O—(C2-C6)alkenyl, (C1-C4)alkyl-O—(C1-C4)alkyl, (C1-C4)alkyl-S(O)n—(C1-C4)alkyl, C(O)—(C1-C4)alkyl-C(O)O—(C1-C4)alkyl, phenyl, and phenoxy; (M) n are each independently 0, 1, or 2; and N-oxides, agriculturally acceptable acid addition salts, salt derivatives, solvates, crystal polymorphs, isotopes, resolved stereoisomers, and tautomers, of the molecules of Formula One.