发明名称 COMPLEXES
摘要 A palladium(II) complex of formula (1) or a palladium(II) complex of formula (3).;;Also, processes for the preparation of the complexes, and their use in carbon-carbon and carbon-heteroatom coupling reactions.
申请公布号 US2017120231(A1) 申请公布日期 2017.05.04
申请号 US201515317725 申请日期 2015.03.20
申请人 JOHNSON MATTHEY PUBLIC LIMITED COMPANY 发明人 COLACOT Thomas;JON DEANGELIS Andrew
分类号 B01J31/24;C07C213/02;C07C67/343;C07C231/08;C07D317/66;C07D213/74;C07D401/12;C07D471/04;C07D409/12;C07B43/04;C07B37/02;C07B47/00;C07D231/44;C07D215/38;C07D417/12;C07D405/12;C07D207/27;C07D263/22;C07D263/24;C07D277/42;C07D241/20;C07D217/02;C07D213/76;C07D209/08;C07D401/04;C07F15/00 主分类号 B01J31/24
代理机构 代理人
主权项 1. A palladium(II) complex of formula (1): wherein: Pd⊕ is a cationic palladium atom; R1 and R2 are independently organic groups having 1-20 carbon atoms, or R1 and R2 are linked to form a ring structure with E; R3, R4, R5, R6, R7, R8, R9, R10 and R11 are independently —H or organic groups having 1-20 carbon atoms; or R1/R3 or R2/R3 forms a ring structure with the atoms to which they are attached and in this instance R4/R5, R5/R6, R7/R8, R8/R9, R9/R10 or R10/R11 may independently form a ring structure with the carbon atoms to which they are attached or R1, R2, R4, R5, R6, R7, R8, R9, R10 and R11 are as defined above; R12 is an organic group having 1-20 carbon atoms; m is 0, 1, 2, 3, 4 or 5; E is P or As; and X⊖ is a non-coordinated anionic ligand.
地址 London GB