发明名称 TETRADENTATE ORGANIC LIGAND H3-MN-16Bn CONTAINING LONG ALKYL GROUP, PRECURSOR THEREOF, AND METHOD FOR PREPARING THE SAME
摘要 A tetradentate organic ligand H3-MN-16Bn containing a long alkyl group, a precursor thereof, and a method for preparing the same are revealed. A precursor of H3-MN-16Bn, benzyl 16-bromohexadecanate, is obtained by esterification reaction of 16-bromohexadecanoic acid. Then bimolecular nucleophilic substitution reaction (SN2) of Benzyl 16-bromohexadecanate with nitrogen sulfide (N2S2) is carried out to get H3-MN-16Bn that is used as a standard hydrolysis metabolites of non-radioactive 185Re-complex compound.
申请公布号 US2017114009(A1) 申请公布日期 2017.04.27
申请号 US201514921070 申请日期 2015.10.23
申请人 INSTITUTE OF NUCLEAR ENERGY RESEARCH, ATOMIC ENERGY COUNCIL, EXECUTIVE YUAN, R.O.C. 发明人 TSAI JIA-DONG;CHANG YU;LU KUEI-LIN;HSU CHENG-FANG
分类号 C07C323/25;C07C67/08;C07C69/24;C07C319/02 主分类号 C07C323/25
代理机构 代理人
主权项 1. A tetradentate organic ligand H3-MN-16Bn containing a long alkyl group is represented by the following structural formula:
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