Dehydrogenation of cyclic thioethers

摘要

There is disclosed a surprising reaction of an alkane thiol with a catalyst and heat to become dehydrogenated and form a thiophene rather than an expected desulfurization reaction to form the corresponding alkane or alkene. Moreover, there are disclosed surprising results regarding the form of a catalyst to allow a reaction of an alkane thiol to form the dehydrogenated thiophene at lower temperatures and at higher conversion percentages to allow for more efficient recovery of thiophenes to allow for recycling and reuse of thiophenes to hydrogenate to form alkane thiols. Further still, there is disclosed a set of reaction conditions and catalyst presentation that allows for recovery of usable diatomic hydrogen gas from a dehydrogenation reaction of substituted or unsubstituted cyclic thioethers to substituted or unsubstituted thiophene.

主权项

1. A process for the delivery of hydrogen from an organic compound capable of reversible hydrogenation/dehydrogenation wherein the organic compound is initially in its hydrogenated form and subsequently catalytically dehydrogenated under dehydrogenation conditions in a reactor forming hydrogen and byproduct dehydrogenated organic compound, comprising:
(a) introducing the organic compound capable of reversible hydrogenation/dehydrogenation in liquid form to a microchannel reactor incorporating a dehydrogenation catalyst; (b) vaporizing the organic compound in a vaporizer; (c) effecting dehydrogenation of the organic compound (d) recovering a reaction product comprised of a byproduct dehydrogenated organiccompound and gaseous hydrogen; and
(e) separating and recovering the reaction product comprised of the dehydrogenated organic compound and gaseous hydrogen into a gaseous hydrogen fraction and liquid phase byproduct dehydrogenated organic compound.